Despite the rapid development of the United Arab Emirates (UAE) and its modern infrastructure, the impact of culture on organizational learning is still very different from western culture. In the UAE, studies on organizational learning are limited. Previous studies reported that employees in police sector have less knowledge management to control the cases specially during the investigation. Therefore, aim of this paper will assessing organizational learning framework in Abu Dhabi police department towards organizational excellence. This research purely quantitative method the questionnaire survey. A total of 291 questionnaire sets were considered adequate in accordance with the sampling methods used to determine the sample size. These were therefore administered to randomly selected respondents in the Abu Dhabi UAE police sector. The analysis of data using appropriate statistical techniques statistical package for social sciences (SPSS) and structural equation modelling (SEM) as the research is quantitative in nature.This study showed Organizational Learning significantly effects on the Organizational Excellence. Furthermore, this model can be applying to Abu Dhabi police under the responsibility of the police sector to ensure that it operates effectively and efficiently, it cooperates with local, national and international organizations to ensure the enforcement of laws in the latter safeguard public safety and maintain law and order.